一种基于原子转移自由基聚合制备结构明确的含二硒键响应性聚合物的简便方法。
A Straightforward Method for Preparing Well-Defined Responsive Diselenide-Containing Polymers Based on ATRP.
作者信息
Fan Caiwei, Ding Chunlai, Pan Xiangqiang, Zhang Zhengbiao, Zhu Jian, Zhu Xiulin
机构信息
Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, P.R. China.
出版信息
Macromol Rapid Commun. 2015 May;36(10):903-8. doi: 10.1002/marc.201500034. Epub 2015 Mar 30.
Diselenide-containing polymers are facilely synthesized from polymers prepared by atom transfer radical polymerization (ATRP). Benefiting from the ATRP technology, this protocol provides a flexible route for controlling the polymer structure, which allows for a great variety of architectures of selenium-containing polymer materials for applications in various fields. The oxidative and reductive responsive behavior of the obtained diselenide-containing polymers is also investigated.
含二硒键的聚合物可通过原子转移自由基聚合（ATRP）制备的聚合物轻松合成。受益于ATRP技术，该方案为控制聚合物结构提供了一条灵活的途径，这使得含硒聚合物材料具有多种结构，可应用于各个领域。还研究了所得含二硒键聚合物的氧化和还原响应行为。
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