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混合碳纳米管-氧化石墨烯作为纳米添加剂在高真空中增强离子液体摩擦性能的协同效应。

Synergistic effect of hybrid carbon nanotube-graphene oxide as nanoadditive enhancing the frictional properties of ionic liquids in high vacuum.

作者信息

Zhang Lili, Pu Jibin, Wang Liping, Xue Qunji

机构信息

†State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, No. 18, Tianshui Middle Road, Lanzhou 730000, P. R. China.

‡University of Chinese Academy of Sciences, Beijing 100039, P. R. China.

出版信息

ACS Appl Mater Interfaces. 2015 Apr 29;7(16):8592-600. doi: 10.1021/acsami.5b00598. Epub 2015 Apr 14.

Abstract

A remarkable synergetic effect between the graphene oxide (GO) layers and multiwalled carbon nanotubes (MWCNTs) in improving friction and wear on sliding diamond-like carbon (DLC) surfaces under high vacuum condition (10(-5) Pa) and low or high applied load is demonstrated. In tests with sliding DLC surfaces, ionic liquid solution that contains small amounts of GO and MWCNTs exhibited the lowest specific friction coefficient and wear rate under all of the sliding conditions. Optical microscope images of the wear scar of a steel ball showed that GO/MWCNT composites exhibited higher antiwear capability than individual MWCNTs and GO did. Transmission electron microscopy images of nanoadditives after friction testing showed that MWCNTs support the GO layers like pillars and prevent assembly between the GO layers. Their synergistic effect considerably enhances IL-GO/MWCNT composites.

摘要

结果表明,在高真空条件(10⁻⁵ 帕)以及低或高加载条件下,氧化石墨烯(GO)层与多壁碳纳米管(MWCNT)之间在改善类金刚石碳(DLC)滑动表面的摩擦和磨损方面具有显著的协同效应。在DLC滑动表面测试中,含有少量GO和MWCNT的离子液体溶液在所有滑动条件下均表现出最低的比摩擦系数和磨损率。钢球磨损痕迹的光学显微镜图像显示,GO/MWCNT复合材料比单独的MWCNT和GO具有更高的抗磨损能力。摩擦测试后纳米添加剂的透射电子显微镜图像表明,MWCNT像柱子一样支撑着GO层,并防止GO层之间的聚集。它们的协同效应显著增强了IL-GO/MWCNT复合材料。

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