Institute of Molecular Functional Materials (Areas of Excellence Scheme, University Grants Committee (Hong Kong)) and Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong.
J Am Chem Soc. 2015 Apr 15;137(14):4654-7. doi: 10.1021/jacs.5b02113. Epub 2015 Apr 1.
A bis-cyclometalated alkynylgold(III) complex, [Au((t)BuC^N^C(t)Bu)(C≡C-C6H4N(C6H5)2-p)] ((t)BuHC^N^CH(t)Bu = 2,6-bis(4-tert-butylphenyl)pyridine), has been synthesized and characterized. The complex was found to exhibit rich photophysical and electrochemical properties. More interestingly, the complex has been employed in the fabrication of organic memory devices. The as-fabricated memory devices exhibited good performances with low operating voltage, high ON/OFF ratio, long retention time, and good stability.
一种双环金属化炔基金(III)配合物，[Au((t)BuC^N^C(t)Bu)(C≡C-C6H4N(C6H5)2-p)] ((t)BuHC^N^CH(t)Bu = 2,6-双(4-叔丁基苯基)吡啶)，已经被合成并进行了表征。该配合物被发现具有丰富的光物理和电化学性质。更有趣的是，该配合物已经被应用于有机存储器件的制造。所制备的存储器件具有低操作电压、高 ON/OFF 比、长保持时间和良好稳定性等优异性能。
