两个具有反向自旋密度分布的磷烯自由基阳离子。
Two phosphaalkene radical cations with inverse spin density distributions.
作者信息
Pan Xiaobo, Wang Xingyong, Zhang Zaichao, Wang Xinping
机构信息
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China.
出版信息
Dalton Trans. 2015 Sep 14;44(34):15099-102. doi: 10.1039/c5dt00656b.
PMID:25828200
Abstract
Two phosphaalkene radical cations 1(•+) and 2(•+) have been reported. 1(•+) is stable in the solid state and has been structurally characterized. 2(•+) only remains persistent in solution. 1(•+) is described as a phosphorus-centered radical, while 2(•+) as a delocalized radical with little contribution from phosphorus.
摘要
已报道了两种磷烯自由基阳离子1(•+)和2(•+)。1(•+)在固态下稳定且已进行了结构表征。2(•+)仅在溶液中保持稳定。1(•+)被描述为以磷为中心的自由基，而2(•+)是一种离域自由基，磷的贡献很小。
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