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用于高效去除水中汞离子的石墨烯-硅藻土气凝胶

Graphene-Diatom Silica Aerogels for Efficient Removal of Mercury Ions from Water.

作者信息

Kabiri Shervin, Tran Diana N H, Azari Sara, Losic Dusan

机构信息

School of Chemical Engineering, The University of Adelaide, Adelaide, SA 5005, Australia.

出版信息

ACS Appl Mater Interfaces. 2015 Jun 10;7(22):11815-23. doi: 10.1021/acsami.5b01159. Epub 2015 May 29.

Abstract

A simple synthetic approach for the preparation of graphene-diatom silica composites in the form of self-assembled aerogels with three-dimensional networks from natural graphite and diatomite rocks is demonstrated for the first time. Their adsorption performance for the removal of mercury from water was studied as a function of contact time, solution pH, and mercury concentration to optimize the reaction conditions. The adsorption isotherm of mercury fitted well with the Langmuir model, representing a very high adsorption capacity of >500 mg of mercury/g of adsorbent. The prepared aerogels exhibited outstanding adsorption performance for the removal of mercury from water, which is significant for environmental applications.

摘要

首次展示了一种简单的合成方法,用于从天然石墨和硅藻土制备具有三维网络的自组装气凝胶形式的石墨烯-硅藻土复合材料。研究了它们从水中去除汞的吸附性能与接触时间、溶液pH值和汞浓度的关系,以优化反应条件。汞的吸附等温线与朗缪尔模型拟合良好,表明吸附剂对汞的吸附容量非常高,大于500毫克汞/克吸附剂。制备的气凝胶在从水中去除汞方面表现出优异的吸附性能,这在环境应用中具有重要意义。

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