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通过原位拉曼光谱研究的机械化学反应：液体辅助研磨中的碱催化

Mechanochemical reactions studied by in situ Raman spectroscopy: base catalysis in liquid-assisted grinding.

作者信息

Tireli Martina, Juribašić Kulcsár Marina, Cindro Nikola, Gracin Davor, Biliškov Nikola, Borovina Mladen, Ćurić Manda, Halasz Ivan, Užarević Krunoslav

机构信息

Ruđer Bošković Institute, Bijenička 54, HR-10000 Zagreb, Croatia.

出版信息

Chem Commun (Camb). 2015 May 11;51(38):8058-61. doi: 10.1039/c5cc01915j. Epub 2015 Apr 13.

DOI:10.1039/c5cc01915j
PMID:25866133
Abstract

In situ Raman spectroscopy was employed to study the course of a mechanochemical nucleophilic substitution on a carbonyl group. We describe evidence of base catalysis, akin to catalysis in solution, achieved by liquid-assisted grinding.

摘要

采用原位拉曼光谱研究羰基上的机械化学亲核取代过程。我们描述了通过液体辅助研磨实现的碱催化证据，这类似于溶液中的催化作用。

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