配位聚合物去溶剂化中的拓扑化学控制。
Topochemical control in desolvation of coordination polymers.
机构信息
Chemical and Environmental Science, University of Limerick , Limerick, Ireland.
出版信息
IUCrJ. 2015 Feb 26;2(Pt 2):166-7. doi: 10.1107/S2052252515003395. eCollection 2015 Mar 1.
Abstract
Reactions in the solid state are at the core of crystal engineering as they can result in new crystalline phases that are not always accessible by traditional solution methods. The work of Brammer and co-workers [Wright et al. (2015), IUCrJ, 2, 188-197] represents a clear example of this potential as applied to the synthesis of a silver-phenazine coordination polymer.
摘要
固态反应是晶体工程的核心，因为它们可以产生新的晶体相，而这些晶体相并不总是可以通过传统的溶液方法获得。Brammer 及其同事的工作[Wright 等人（2015），IUCrJ，2，188-197]就是一个很好的例子，证明了这一方法在合成银-吩嗪配位聚合物中的潜力。
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