Natural Products Laboratory, School of Pharmacy, Sungkyunkwan University, 2066 Seobu-ro, Jangan-ku, Suwon, 440-746, Korea.
Arch Pharm Res. 2015 Jul;38(7):1312-6. doi: 10.1007/s12272-015-0603-x. Epub 2015 Apr 14.
A phytochemical investigation of Allium tuberosum Rottler afforded two new phenylpropane glycosides, named tuberonoid A (1) and B (2), along with four known flavonoids, kaempferol 3-O-β-sophoroside (3), 3-O-β-D-(2-O-feruloyl)-glucosyl-7,4'-di-O-β-D-glucosylkaempferol (4), 3-O-β-sophorosyl-7-O-β-D-(2-O-feruloyl)glucosyl kaempferol (5), kaempferol 3,4'-di-O-β-D-glucoside (6). The identification and structural elucidation of the new compounds were carried out based on spectral data analyses ((1)H and (13)C NMR, (1)H-(1)H COSY, HMQC) and HR-MS.
从葱属植物中提取的化学成分分析得到了两种新的苯丙烷糖苷,分别命名为tuberonoid A(1)和 B(2),以及四种已知的类黄酮,山柰酚 3-O-β-槐糖苷(3)、3-O-β-D-(2-O-阿魏酰基)-葡萄糖基-7,4'-二-O-β-D-葡萄糖基山柰酚(4)、3-O-β-槐糖苷基-7-O-β-D-(2-O-阿魏酰基)葡萄糖基山柰酚(5)和山柰酚 3,4'-二-O-β-D-葡萄糖苷(6)。根据光谱数据分析(1H 和 13C NMR、1H-1H COSY、HMQC 和 HR-MS)对新化合物进行了鉴定和结构解析。