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欧洲污水污泥中的多环芳烃含量及其作为土壤肥料的用途。

PAHs content of sewage sludge in Europe and its use as soil fertilizer.

作者信息

Suciu Nicoleta A, Lamastra Lucrezia, Trevisan Marco

机构信息

Istituto di Chimica Agraria ed Ambientale, Università Cattolica del Sacro Cuore, via Emilia Parmense 84, Piacenza 29122, Italy.

Istituto di Chimica Agraria ed Ambientale, Università Cattolica del Sacro Cuore, via Emilia Parmense 84, Piacenza 29122, Italy.

出版信息

Waste Manag. 2015 Jul;41:119-27. doi: 10.1016/j.wasman.2015.03.018. Epub 2015 Apr 11.

Abstract

The European Commission has been planning limits for organic pollutants in sewage sludge for 14years; however no legislation has been implemented. This is mainly due to lack of data on sewage sludge contamination by organic pollutants, and possible negative effects to the environment. However, waste management has become an acute problem in many countries. Management options require extensive waste characterization, since many of them may contain compounds which could be harmful to the ecosystem, such as heavy metals, organic pollutants. The present study aims to show the true European position, regarding the polycyclic aromatic hydrocarbons (PAHs) content of sewage sludge, by comparing the Italian PAHs content with European Union countries, and at assessing the suitability of sewage sludge as soil fertilizer. The FOCUS Pearl model was used to estimate the concentration of benzo [a] pyrene (B(a)Pyr), the most toxic PAH in soil, and its exposure to organisms was then evaluated. The simulated B(a)Pyr and PAHs, expressed as B(a)Pyr, concentrations in soil were much lower than the B(a)Pyr's most conservative lowest observable effect concentration (LOEC) for soil organisms. Furthermore, the results obtained indicate that it is more appropriate to apply 5tha(-1) sewage sludge annually than 15tha(-1) triennially. Results suggest, the EU maximum recommended limit of 6mgkg(-)(1) PAHs in sewage sludge, should be conservative enough to avoid groundwater contamination and negative effects on soil organisms.

摘要

14年来,欧盟委员会一直在规划污水污泥中有机污染物的限值;然而,尚未实施相关立法。这主要是由于缺乏关于有机污染物对污水污泥污染的数据,以及对环境可能产生的负面影响。然而,废物管理在许多国家已成为一个严峻的问题。管理方案需要对废物进行广泛的特性描述,因为其中许多可能含有对生态系统有害的化合物,如重金属、有机污染物。本研究旨在通过比较意大利与欧盟国家污水污泥中多环芳烃(PAHs)的含量,展示欧盟在这方面的真实情况,并评估污水污泥作为土壤肥料的适用性。使用FOCUS Pearl模型估算土壤中毒性最强的多环芳烃苯并[a]芘(B(a)Pyr)的浓度,然后评估其对生物体的暴露情况。模拟得到的土壤中B(a)Pyr和以B(a)Pyr表示的多环芳烃浓度远低于土壤生物最保守的最低可观察效应浓度(LOEC)。此外,所得结果表明,每年施用5吨/公顷的污水污泥比每三年施用15吨/公顷更为合适。结果表明,欧盟建议的污水污泥中多环芳烃的最大限量6毫克/千克应该足够保守,以避免地下水污染和对土壤生物产生负面影响。

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