通过肽缀合实现晶体学洞察引导的n型有机半导体的纳米结构设计与电导率调制
Crystallographic insight-guided nanoarchitectonics and conductivity modulation of an n-type organic semiconductor through peptide conjugation.
作者信息
Pandeeswar M, Khare Harshavardhan, Ramakumar Suryanarayanarao, Govindaraju T
机构信息
Bioorganic Chemistry Laboratory, New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur P.O., Bengaluru 560064, India.
出版信息
Chem Commun (Camb). 2015 May 14;51(39):8315-8. doi: 10.1039/c5cc01996f.
Crystallographic insight-guided nanoarchitectonics of peptide-conjugated naphthalene diimide (NDI) is described. In a bio-inspired approach, non-proteinogenic α-amino isobutyric acid (Aib)- and alanine (Ala)-derived peptides orchestrated the 1D achiral and 2D chiral molecular ordering of NDI, respectively, which resulted in modulation of nanoscale morphology, chiroptical and conductivity properties.
描述了基于晶体学见解的肽共轭萘二酰亚胺（NDI）的纳米结构设计。采用受生物启发的方法，分别由非蛋白ogenicα-氨基异丁酸（Aib）和丙氨酸（Ala）衍生的肽编排了NDI的一维非手性和二维手性分子排列，这导致了纳米级形态、手性光学和导电性能的调制。
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