Shi Zhi-Qiang, Guo Zi-Jian, Zheng He-Gen
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, P. R. China.
Chem Commun (Camb). 2015 May 14;51(39):8300-3. doi: 10.1039/c5cc00987a.
Two luminescent Zn(II) metal-organic frameworks were prepared from a π-conjugated thiophene-containing carboxylic acid ligand. These two MOFs show strong luminescene and their luminescence could be quenched by a series of nitroaromatic explosives. Importantly, they exhibit very highly sensitive and selective detection of picric acid compared to other nitroaromatic explosives.
通过含π共轭噻吩的羧酸配体制备了两种发光锌（II）金属有机框架材料。这两种金属有机框架材料显示出强发光性，并且它们的发光能够被一系列硝基芳香族炸药淬灭。重要的是，与其他硝基芳香族炸药相比，它们对苦味酸表现出非常高的灵敏度和选择性检测。
