Shen Mingyue, Liu Qian, Jiang Yujie, Nie Shaoping, Zhang Yanan, Xie Jianhua, Wang Sunan, Zhu Fan, Xie Mingyong
State Key Laboratory of Food Science and Technology, Nanchang University, Nanchang, 330047, China.
Canadian Food and Wine Institute, Niagara College, 135 Taylor Road, Niagara-on-the-Lake, Ontario, LOS 1JO, Canada.
J Food Sci. 2015 Jun;80(6):T1432-7. doi: 10.1111/1750-3841.12864. Epub 2015 Apr 27.
Furan, a possible carcinogen, is commonly produced by thermal processing in a number of heated foods. The existence of furan levels in foods has attracted considerable attention worldwide. Recent research of furan in food has focused on the possible influences of operating parameters on the furan formation during heat processing. The aim of our study was to investigate the impacts of multiple factors (pH, temperature, heating time, ferric, and glutamic acid) on furan formation using linolenic and linoleic acids-based model systems in which furan was analyzed by headspace gas chromatography-mass spectrometry (HS-GC-MS). The results revealed that the content of furan increased rapidly when the heating temperature was elevated, with the highest levels of furan in neutral buffer solutions, the furan levels were also found to be related to heating time in all model systems. Ferric promoted furan formation from polyunsaturated fatty acids, conversely glutamic acid with an optimum concentration suppressed the furan formation. The minimal level of furan in foods during thermal treatment could be achieved via adding furan formation suppressors, and/or avoidance of furan forming promoter.
呋喃是一种可能的致癌物,通常在许多加热食品的热加工过程中产生。食品中呋喃含量的存在已引起全球广泛关注。近期对食品中呋喃的研究集中在热加工过程中操作参数对呋喃形成的可能影响。我们研究的目的是使用基于亚麻酸和亚油酸的模型系统,通过顶空气相色谱 - 质谱联用仪(HS - GC - MS)分析呋喃,来研究多种因素(pH值、温度、加热时间、铁离子和谷氨酸)对呋喃形成的影响。结果表明,加热温度升高时,呋喃含量迅速增加,在中性缓冲溶液中呋喃含量最高,在所有模型系统中,呋喃含量也与加热时间有关。铁离子促进多不饱和脂肪酸形成呋喃,相反,具有最佳浓度的谷氨酸抑制呋喃形成。通过添加呋喃形成抑制剂和/或避免呋喃形成促进剂,可以实现热处理过程中食品中呋喃的最低含量。