Capreti Naylil M R, Jurberg Igor D
Institute of Chemistry, State University of Campinas, 13083-970, C.P. 6154, Campinas, SP, Brazil.
Org Lett. 2015 May 15;17(10):2490-3. doi: 10.1021/acs.orglett.5b01004. Epub 2015 Apr 30.
A novel, divergent strategy toward the synthesis of β-branched (and linear) carbonyl compounds is developed by taking advantage of alkylidene isoxazol-5-ones as key building blocks. The yields obtained range from good to excellent, therefore making the described methods attractive options for building such molecules.
通过利用亚烷基异恶唑-5-酮作为关键构建单元，开发了一种新颖、不同的合成β-支链（和直链）羰基化合物的策略。所获得的产率从良好到优异不等，因此使得所描述的方法成为构建此类分子的有吸引力的选择。
