J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of Czech Republic, v.v.i. Dolejškova 3, 182 23 Prague 8, Czech Republic.
Chem Soc Rev. 2015 Oct 21;44(20):7177-206. doi: 10.1039/c5cs00045a. Epub 2015 May 6.
A novel methodology, called ADOR (assembly-disassembly-organisation-reassembly), for the synthesis of zeolites is reviewed here in detail. The ADOR mechanism stems from the fact that certain chemical weakness against a stimulus may be present in a zeolite framework, which can then be utilized for the preparation of new solids through successive manipulation of the material. In this review, we discuss the critical factors of germanosilicate zeolites required for application of the ADOR protocol and describe the mechanism of hydrolysis, organisation and condensation to form new zeolites starting from zeolite UTL. Last but not least, we discuss the potential of this methodology to form other zeolites and the prospects for future investigations.
本文详细回顾了一种称为 ADOR（组装-拆卸-组织-再组装）的沸石合成新方法。ADOR 机制源于沸石骨架中存在对刺激的某些化学弱点，然后可以通过对材料的连续操作来利用该弱点制备新的固体。在本综述中，我们讨论了应用 ADOR 方案所需的锗硅酸盐沸石的关键因素，并描述了从 UTL 沸石开始水解、组织和缩合形成新沸石的机制。最后但同样重要的是，我们讨论了该方法形成其他沸石的潜力以及未来研究的前景。
