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发光金纳米粒子:基于等离子体共振能量转移的新型传感方法。

Brightening gold nanoparticles: new sensing approach based on plasmon resonance energy transfer.

作者信息

Shi Lei, Jing Chao, Gu Zhen, Long Yi-Tao

机构信息

Key Laboratory for Advanced Materials &Department of Chemistry, East China University of Science and Technology, Shanghai 200237, P. R. China.

出版信息

Sci Rep. 2015 May 11;5:10142. doi: 10.1038/srep10142.

Abstract

Scattering recovered plasmonic resonance energy transfer (SR-PRET) was reported by blocking the plasmon resonance energy transfer (PRET) from gold nanoparticle (GNP) to the adsorbed molecules (RdBS). Due to the selective cleavage of the Si-O bond by F- ions, the quenching is switched off causing an increase in the brightness of the GNPs,detected using dark-field microscopy (DFM) were brightened. This method was successfully applied to the determination of fluoride ions in water. The SR-PRET provides a potential approach for a vitro/vivo sensing with high sensitivity and selectivity.

摘要

通过阻断从金纳米颗粒(GNP)到吸附分子(RdBS)的等离子体共振能量转移(PRET),报道了散射恢复等离子体共振能量转移(SR-PRET)。由于F-离子对Si-O键的选择性裂解,猝灭被关闭,导致GNP的亮度增加,使用暗场显微镜(DFM)检测到其亮度增强。该方法已成功应用于水中氟离子的测定。SR-PRET为体外/体内高灵敏度和高选择性传感提供了一种潜在方法。

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