Jo Yong Deok, Lee Sooken, Seo Jeongeun, Lee Soobum, Ann Doyeon, Lee Haiwon
J Nanosci Nanotechnol. 2014 Dec;14(12):9148-51. doi: 10.1166/jnn.2014.10092.
Ammonia (NH3) gas is one of the gases which causes damage to environment such as acidification and climate change. In this study, a gas sensor based on the three-dimensional (3D) network of single-walled nanotubes (SWNTs) was fabricated for the detection of NH3 gas in dry air. The sensor showed enhanced performance due to the fast gas diffusion rate and weak interactions between the carbon nanotubes and the substrate. Metal oxide particles were introduced to enhance the performance of the gas sensor. Atomic layer deposition (ALD) was employed to deposit the metal oxide in the complex structure, and good control over thickness was achieved. The hybrid gas sensor consisting of the 3D network of SWNTs with anatase TiO2 particles showed stable, repeatable, and enhanced gas sensor performance. The phase of TiO2 particles was characterized by Raman and the morphology of the TiO2 particles on the 3D network of SWNTs was analyzed by transmission electron microscope.
氨气(NH₃)是导致环境酸化和气候变化等环境破坏的气体之一。在本研究中,制备了一种基于单壁纳米管(SWNTs)三维(3D)网络的气体传感器,用于检测干燥空气中的NH₃气体。由于气体扩散速率快以及碳纳米管与基底之间的相互作用较弱,该传感器表现出增强的性能。引入金属氧化物颗粒以提高气体传感器的性能。采用原子层沉积(ALD)在复杂结构中沉积金属氧化物,并实现了对厚度的良好控制。由具有锐钛矿型TiO₂颗粒的SWNTs三维网络组成的混合气体传感器表现出稳定、可重复且增强的气体传感器性能。通过拉曼光谱对TiO₂颗粒的相进行了表征,并通过透射电子显微镜分析了SWNTs三维网络上TiO₂颗粒的形态。