Department of Chemistry, Quaid-i-Azam University, 45320 Islamabad, Pakistan.
Department of Biomedical, Chemical and Environmental Engineering, Cincinnati, OH 45221-0012, USA.
J Photochem Photobiol B. 2015 Jul;148:209-222. doi: 10.1016/j.jphotobiol.2015.04.020. Epub 2015 Apr 30.
One of the main goals of organic chemists is to find easy, environmentally friendly, and cost effective methods for the synthesis of industrially important compounds. Photocatalysts have brought revolution in this regard as they make use of unlimited source of energy (the solar light) to carry out the synthesis of organic compounds having otherwise complex synthetic procedures. However, selectivity of the products has been a major issue since the beginning of photocatalysis. The present article encompasses state of the art accomplishments in harvesting light energy for selective organic transformations using photocatalysts. Several approaches for the development of photocatalysts for selective organic conversions have been critically discussed with the objective of developing efficient, selective, environmental friendly and high yield photocatalytic methodologies.
有机化学家的主要目标之一是找到简单、环保且具有成本效益的方法来合成具有工业重要性的化合物。光催化剂在这方面带来了革命,因为它们利用无限的能源(太阳光)来进行具有复杂合成步骤的有机化合物的合成。然而,自光催化开始以来,产品的选择性一直是一个主要问题。本文涵盖了利用光催化剂为选择性有机转化收集光能的最新成就。本文批判性地讨论了几种开发用于选择性有机转化的光催化剂的方法,目的是开发高效、选择性、环保和高产的光催化方法。