State Key Laboratory Breeding Base of Photocatalysis, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, Fujian, PR China.
Nanoscale. 2012 Sep 28;4(19):5792-813. doi: 10.1039/c2nr31480k. Epub 2012 Aug 20.
Graphene (GR) has become a sparkling rising star on the horizon of material science. Due to its unique planar structure, excellent transparency, superior electron conductivity and mobility, high specific surface area, and high chemical stability, GR is regarded as an ideal high performance candidate to prepare GR-based nanocomposites for energy storage and conversion. During the past few years, GR-based photocatalysts have been attracting ever-increasing research attention. In this tutorial review, the applications of GR-based nanocomposites in photocatalysis, including nonselective processes for degradation of pollutants, selective transformations for organic synthesis and water splitting to clean hydrogen energy, are summarized systematically. In particular, in addition to discussing opportunities offered by GR, we will also describe the existing challenges for future exploitation and development of GR-based nanocomposites, which we hope would significantly advance us to rationally and efficiently harness the outstanding structural and electronic properties of GR to design smarter and more efficient GR-based photocatalysts instead of joining the graphene "gold rush".
石墨烯(GR)已成为材料科学领域中一颗耀眼的新星。由于其独特的平面结构、优异的透光性、卓越的电子导电性和迁移率、高比表面积和高化学稳定性,GR 被视为制备用于储能和转换的基于 GR 的纳米复合材料的理想高性能候选材料。在过去的几年中,基于 GR 的光催化剂引起了越来越多的研究关注。在本综述中,系统地总结了基于 GR 的纳米复合材料在光催化中的应用,包括污染物非选择性降解、有机合成选择性转化以及水分解清洁氢能。特别是,除了讨论 GR 提供的机会外,我们还将描述未来开发基于 GR 的纳米复合材料所面临的挑战,我们希望这将极大地推动我们合理有效地利用 GR 的出色结构和电子特性,设计更智能、更高效的基于 GR 的光催化剂,而不是盲目跟风参与“石墨烯淘金热”。