在水中用对甲苯磺酰芳基重氮盐进行松田-赫克反应。
Matsuda-Heck reaction with arenediazonium tosylates in water.
作者信息
Kutonova Ksenia V, Trusova Marina E, Stankevich Andrey V, Postnikov Pavel S, Filimonov Victor D
机构信息
Department of Biotechnology and Organic Chemistry, National Research Tomsk Polytechnic University, 634050 Tomsk, Russia.
Laboratory of Materials and Technologies of Liquid Crystal Devices, Institute of Chemistry of New Materials NAS Belarus, 220141, Minsk, Belarus.
出版信息
Beilstein J Org Chem. 2015 Mar 16;11:358-62. doi: 10.3762/bjoc.11.41. eCollection 2015.
An environmentally friendly Matsuda-Heck reaction with arenediazonium tosylates has been developed for the first time. A range of alkenes was arylated in good to quantitative yields in water. The reaction is significantly accelerated when carried out under microwave heating. The arylation of haloalkylacrylates with diazonium salts has been implemented for the first time.
首次开发了一种使用芳基重氮甲苯磺酸盐的环境友好型松田-赫克反应。一系列烯烃在水中以良好至定量的产率进行了芳基化反应。在微波加热下进行该反应时，反应显著加速。首次实现了卤代烷基丙烯酸酯与重氮盐的芳基化反应。
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