Yu Xiao, Cohen Seth M
Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093, USA.
Chem Commun (Camb). 2015 Jun 18;51(48):9880-3. doi: 10.1039/c5cc01697e.
A photocatalytic Ru complex was incorporated into a Zr(iv)-based metal-organic framework (MOF) via postsynthetic methods. The resulting UiO-67-Ru(bpy)3 shows efficient and recyclable catalytic activity for the aerobic oxidation of arylboronic acids under near-UV and visible light irradiation.
通过后合成方法将一种光催化钌配合物引入基于锆（IV）的金属有机框架（MOF）中。所得的UiO-67-Ru(bpy)3在近紫外光和可见光照射下对芳基硼酸的有氧氧化显示出高效且可循环的催化活性。
