Li Bijian, Gui Bo, Hu Guiping, Yuan Daqiang, Wang Cheng
†Key Laboratory of Biomedical Polymers (Ministry of Education), College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China.
‡State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China.
Inorg Chem. 2015 Jun 1;54(11):5139-41. doi: 10.1021/acs.inorgchem.5b00535. Epub 2015 May 8.
Herein, we report the synthesis and postsynthetic modification of a novel alkyne-tagged zirconium metal-organic framework, UiO-68-alkyne. The alkynyl groups in the pore surface were subjected to a "click" reaction, achieving quantitative conversion and maintaining the crystallinity of the framework.
在此，我们报告了一种新型炔基标记的锆金属有机框架UiO-68-炔的合成及合成后修饰。孔表面的炔基进行了“点击”反应，实现了定量转化并保持了框架的结晶度。
