Mague Joel T, Mohamed Shaaban K, Akkurt Mehmet, El-Saghier Ahmed M M, Albayati Mustafa R
Department of Chemistry, Tulane University, New Orleans, LA 70118, USA.
Chemistry and Environmental Division, Manchester Metropolitan University, Manchester M1 5GD, England ; Chemistry Department, Faculty of Science, Minia University, 61519 El-Minia, Egypt.
Acta Crystallogr E Crystallogr Commun. 2015 Apr 9;71(Pt 5):m102-3. doi: 10.1107/S2056989015006325. eCollection 2015 May 1.
In the title compound, [Na(C10H5ClN5)(H2O)2] n , infinite chains of Na(H2O)2 cations having a diamond-shaped cross-section and running parallel to the b axis are formed. O-H⋯N hydrogen bonds to the anions generate layers parallel to (100) which have the chloro-benzene-cyano-ethenyl substituents protruding from both surfaces. The sodium ion makes a short contact of 2.4801 (13) Å with the N atom of the tetra-zolide ring which is syn to the cyano N atom.
在标题化合物[Na(C₁₀H₅ClN₅)(H₂O)₂]ₙ中，形成了具有菱形横截面且平行于b轴的[Na(H₂O)₂]⁺阳离子的无限链。与阴离子的O—H⋯N氢键形成平行于(100)的层，该层具有从两个表面突出的氯苯 - 氰基 - 乙烯基取代基。钠离子与四唑环的N原子形成2.4801(13) Å的短接触，该N原子与氰基N原子呈顺式。
