• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

双-[4-(二甲基氨基)-吡啶-κN(1)]双-(甲醇-κO)双-(硫氰酸根-κN)锰(II)的晶体结构

Crystal structure of bis-[4-(di-methyl-amino)-pyridine-κN (1)]bis-(methanol-κO)bis-(thio-cyanato-κN)manganese(II).

作者信息

Suckert Stefan, Jess Inke, Näther Christian

机构信息

Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Strasse 2, 24118 Kiel, Germany.

出版信息

Acta Crystallogr E Crystallogr Commun. 2015 Apr 30;71(Pt 5):m126. doi: 10.1107/S2056989015007318. eCollection 2015 May 1.

DOI:10.1107/S2056989015007318
PMID:25995897
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4420091/
Abstract

The whole mol-ecule of the title compound, [Mn(NCS)2(CH3OH)2(C5H6N2)2], is generated by inversion symmetry. The Mn(II) ion, which is located on an inversion center, is coordinated by two 4-(di-methyl-amino)-pyridine ligands, two methanol ligands and two terminally N-bonded thio-cyanate anions, forming a slightly distorted octa-hedron. In the crystal, mol-ecules are linked by O-H⋯S hydrogen bonds, forming chains extending along the a-axis direction.

摘要

标题化合物[Mn(NCS)₂(CH₃OH)₂(C₅H₆N₂)₂]的整个分子由反演对称性产生。位于反演中心的Mn(II)离子由两个4-(二甲基氨基)吡啶配体、两个甲醇配体和两个末端N键合的硫氰酸根阴离子配位，形成一个略微扭曲的八面体。在晶体中，分子通过O—H⋯S氢键相连，形成沿a轴方向延伸的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8dc2/4420091/7a0ae0e62a06/e-71-0m126-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8dc2/4420091/76a0680fd218/e-71-0m126-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8dc2/4420091/7a0ae0e62a06/e-71-0m126-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8dc2/4420091/76a0680fd218/e-71-0m126-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8dc2/4420091/7a0ae0e62a06/e-71-0m126-fig2.jpg

相似文献

1
Crystal structure of bis-[4-(di-methyl-amino)-pyridine-κN (1)]bis-(methanol-κO)bis-(thio-cyanato-κN)manganese(II).双-[4-(二甲基氨基)-吡啶-κN(1)]双-(甲醇-κO)双-(硫氰酸根-κN)锰(II)的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Apr 30;71(Pt 5):m126. doi: 10.1107/S2056989015007318. eCollection 2015 May 1.
2
Crystal structure of bis(4-benzoyl-pyridine-κ)bis(methanol-κ)bis(thio-cyanato-κ)nickel(II) methanol monosolvate.双（4-苯甲酰基吡啶-κ）双（甲醇-κ）双（硫氰酸根合-κ）镍（II）甲醇单溶剂合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2019 Jan 31;75(Pt 2):299-303. doi: 10.1107/S2056989019001555. eCollection 2019 Feb 1.
3
Crystal structure of bis-(3,5-di-methyl-pyridine-κ)bis-(methanol-κ)bis-(thio-cyanato-κ)cobalt(II).双（3,5-二甲基吡啶-κ）双（甲醇-κ）双（硫氰酸根合-κ）钴（II）的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Nov 18;72(Pt 12):1824-1826. doi: 10.1107/S2056989016018326. eCollection 2016 Dec 1.
4
Crystal structure of bis-(4-acetyl-pyridine-κN)bis-(ethanol-κO)bis-(thio-cyanato-κN)manganese(II).双（4-乙酰基吡啶-κN）双（乙醇-κO）双（硫氰酸根合-κN）锰（II）的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Mar 11;71(Pt 4):m81-2. doi: 10.1107/S2056989015004533. eCollection 2015 Apr 1.
5
Crystal structures of two Co(NCS) urotropine coordination compounds with different Co coordinations.两种具有不同钴配位方式的硫氰酸钴乌洛托品配位化合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2022 Feb 3;78(Pt 3):264-269. doi: 10.1107/S2056989022001037. eCollection 2022 Feb 1.
6
Crystal structures of tetra-kis-(pyridine-4-thio-amide-κ)bis-(thio-cyanato-κ)cobalt(II) monohydrate and bis-(pyridine-4-thio-amide-κ)bis-(thio-cyanato-κ)zinc(II).四 - （吡啶 - 4 - 硫代酰胺 - κ）双 - （硫氰酸根合 - κ）钴（II）一水合物和双 - （吡啶 - 4 - 硫代酰胺 - κ）双 - （硫氰酸根合 - κ）锌（II）的晶体结构
Acta Crystallogr E Crystallogr Commun. 2018 Jan 12;74(Pt 2):141-146. doi: 10.1107/S205698901800021X. eCollection 2018 Feb 1.
7
Crystal structure of bis-(pyridine-4-carbo-thio-amide-κ)bis-(thio-cyanato-κ)cobalt(II) methanol monosolvate.双（吡啶-4-碳硫酰胺-κ）双（硫氰酸根合-κ）钴（II）甲醇单溶剂合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2017 Oct 31;73(Pt 11):1786-1789. doi: 10.1107/S2056989017015055. eCollection 2017 Nov 1.
8
Bis(3-acetyl-pyridine-κN)bis-(methanol-κO)bis-(thio-cyanato-κN)nickel(II).双（3-乙酰基吡啶-κN）双（甲醇-κO）双（硫氰酸根合-κN）镍（II）
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m441-2. doi: 10.1107/S1600536812008860. Epub 2012 Mar 17.
9
Crystal structure of di-aqua-bis-(4-cyano-pyridine-κ)bis-(thio-cyanato-κ)iron(II) 4-cyano-pyridine disolvate.二水合双（4-氰基吡啶-κ）双（硫氰酸根合-κ）铁（II）4-氰基吡啶二溶剂合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2017 Mar 3;73(Pt 4):463-466. doi: 10.1107/S205698901700322X. eCollection 2017 Apr 1.
10
Crystal structure of catena-poly[[[bis-(pyridine-4-carbo-thio-amide-κN (1))cadmium]-di-μ-thio-cyanato-κ(2) N:S;κ(2) S:N] methanol disolvate].链状聚[[[双-(吡啶-4-碳硫酰胺-κN(1))镉]-二-μ-硫氰酸根合-κ(2)N:S;κ(2)S:N]]甲醇溶剂合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Feb 20;72(Pt 3):370-3. doi: 10.1107/S2056989016002632. eCollection 2016 Mar 1.

引用本文的文献

1
Comparison of the crystal structures of the low- and high-temperature forms of bis-[4-(di-methyl-amino)-pyridine]-dithio-cyanato-cobalt(II).双-[4-(二甲基氨基)-吡啶]-二硫氰酸根合钴(II)低温和高温形式的晶体结构比较
Acta Crystallogr E Crystallogr Commun. 2021 Oct 19;77(Pt 11):1120-1125. doi: 10.1107/S2056989021010422. eCollection 2021 Nov 1.
2
Crystal structures of bis-[4-(di-methyl-amino)-pyridinium] tetra-kis-(thio-cyanato-κ)manganate(II) and tris-[4-(di-methyl-amino)-pyridinium] penta-kis(thio-cyanato-κ)manganate(II).双-[4-(二甲基氨基)吡啶鎓]四-(硫氰酸根-κ)锰(II)和三-[4-(二甲基氨基)吡啶鎓]五-(硫氰酸根-κ)锰(II)的晶体结构
Acta Crystallogr E Crystallogr Commun. 2018 Jan 1;74(Pt 1):15-20. doi: 10.1107/S2056989017017510.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.