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Crystal structure of 3-(4-meth-oxy-phen-yl)-2,3-di-hydro-1H-naphtho-[2,1-b]pyran-1-one.

作者信息

Vasanthi R, Reuben Jonathan D, Elizhlarasi K S, Revathi B K, Usha G

机构信息

PG and Research Department of Physics, Queen Mary's College, Chennai-4, Tamilnadu, India.

Department of Chemistry, Madras Christian College, Chennai-59, India.

出版信息

Acta Crystallogr E Crystallogr Commun. 2015 Apr 22;71(Pt 5):o332. doi: 10.1107/S2056989015007082. eCollection 2015 May 1.

Abstract

In the title compound, C20H16O3, the hydro-pyran ring adopts a distorted half-chair conformation with the methine C atom and the ring O atom displaced by -0.554 (2) and 0.158 (1) Å, respectively, from the plane of the other four atoms (r.m.s. deviation = 0.020 Å). Its mean plane (all atoms) is inclined to the naphthalene ring system at a dihedral angle of 11.67 (1)°. The dihedral angle between the napthalene ring system and the phenyl ring is 71.84 (1)°. In the crystal, no diectional inter-actions beyond van der Waals contacts could be identified.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6773/4420115/0c1eae9f57e2/e-71-0o332-fig1.jpg

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