Vasanthi R, Reuben Jonathan D, Ezhilarasi K S, Sathya S, Usha G
PG and Research Department of Physics, Queen Mary's College, Chennai-4, Tamilnadu, India.
Department of Chemistry, Madras Christian College, Chennai-59, India.
Acta Crystallogr Sect E Struct Rep Online. 2014 Sep 20;70(Pt 10):o1116-7. doi: 10.1107/S1600536814020868. eCollection 2014 Oct 1.
In the title compound, C26H20O3, the pyran ring has a distorted half-chair conformation and its mean plane is inclined to the naphthalene ring system, to which it is fused, by 10.79 (9)°. The dihedral angles between the napthalene unit and the benzene and phenyl rings are 54.39 (9) and 52.65 (12)°, respectively, while the benzene and phenyl rings are inclined to one another by 74.80 (14)°. There is a short C-H⋯O contact in the chromen-1-one unit. In the crystal, mol-ecules are linked by two pairs of C-H⋯O hydrogen bonds, forming inversion dimers described by graph set motifs R 2 (2)(8) and R 2 (2)(10), giving rise to chains running parallel to (101). The chains are linked via C-H⋯π inter-actions, forming sheets lying parallel to (010).
在标题化合物C₂₆H₂₀O₃中,吡喃环具有扭曲的半椅构象,其平均平面与稠合的萘环体系倾斜10.79 (9)°。萘单元与苯环和苯环之间的二面角分别为54.39 (9)°和52.65 (12)°,而苯环和苯环相互倾斜74.80 (14)°。色酮-1-酮单元中存在短的C-H⋯O接触。在晶体中,分子通过两对C-H⋯O氢键相连,形成由图集合 motif R 2 (2)(8) 和R 2 (2)(10) 描述的反演二聚体,产生平行于(101) 的链。这些链通过C-H⋯π相互作用相连,形成平行于(010) 的片层。