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酰胺基席夫碱衍生物作为比色氟传感器:硝基取代对灵敏度和颜色变化的影响。

Amido-Schiff base derivatives as colorimetric fluoride sensor: Effect of nitro substitution on the sensitivity and color change.

作者信息

Ghosh Soumen, Alam Md Akhtarul, Ganguly Aniruddha, Guchhait Nikhil

机构信息

Department of Chemistry, University of Calcutta, 92, A.P.C. Road, Kolkata 700 009, India.

Department of Chemistry, Aliah University, DN-18, Sector-V, Saltlake, Kolkata 700091, India.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2015;149:869-74. doi: 10.1016/j.saa.2015.04.025. Epub 2015 May 2.

Abstract

A series of Schiff bases synthesized by the condensation of benzohydrazide and -NO2 substituted benzaldehyde have been used as selective fluoride ion sensor. Test paper coated with these synthetic Schiff bases (test kits) can detect fluoride ion selectively with a drastic color change and detection can be achieved by just using the naked-eye without the help of any optical instrument. Interestingly, the position of -NO2 group in the amido Schiff bases has an effect on the sensitivity as well as on the change of color of species.

摘要

一系列由苯甲酰肼与 -NO₂ 取代苯甲醛缩合合成的席夫碱已被用作选择性氟离子传感器。涂有这些合成席夫碱的试纸(测试试剂盒)能够通过显著的颜色变化选择性地检测氟离子,并且仅用肉眼即可实现检测,无需任何光学仪器的帮助。有趣的是,酰胺基席夫碱中 -NO₂ 基团的位置对灵敏度以及物质颜色的变化都有影响。

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