Ghosh Soumen, Alam Md Akhtarul, Ganguly Aniruddha, Guchhait Nikhil
Department of Chemistry, University of Calcutta, 92, A.P.C. Road, Kolkata 700 009, India.
Department of Chemistry, Aliah University, DN-18, Sector-V, Saltlake, Kolkata 700091, India.
Spectrochim Acta A Mol Biomol Spectrosc. 2015;149:869-74. doi: 10.1016/j.saa.2015.04.025. Epub 2015 May 2.
A series of Schiff bases synthesized by the condensation of benzohydrazide and -NO2 substituted benzaldehyde have been used as selective fluoride ion sensor. Test paper coated with these synthetic Schiff bases (test kits) can detect fluoride ion selectively with a drastic color change and detection can be achieved by just using the naked-eye without the help of any optical instrument. Interestingly, the position of -NO2 group in the amido Schiff bases has an effect on the sensitivity as well as on the change of color of species.
一系列由苯甲酰肼与 -NO₂ 取代苯甲醛缩合合成的席夫碱已被用作选择性氟离子传感器。涂有这些合成席夫碱的试纸(测试试剂盒)能够通过显著的颜色变化选择性地检测氟离子,并且仅用肉眼即可实现检测,无需任何光学仪器的帮助。有趣的是,酰胺基席夫碱中 -NO₂ 基团的位置对灵敏度以及物质颜色的变化都有影响。