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基于希夫碱衍生物的新型高选择性铝(III)离子比色传感器

A novel highly selective colorimetric sensor for aluminum (III) ion using Schiff base derivative.

机构信息

Department of Chemistry & Environmental Science, Minnan Normal University, Zhangzhou 363000, PR China.

Department of Chemistry & Environmental Science, Minnan Normal University, Zhangzhou 363000, PR China.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2014 Mar 25;122:268-72. doi: 10.1016/j.saa.2013.11.063. Epub 2013 Nov 21.

Abstract

A novel colorimetric sensor, 2-hydroxy naphthaldehyde isonicotinoyl hydrazone (HINH), was easily synthesized by the condensation of isoniazid and 2-hydroxy-1-naphthaldehyde. The as-prepared compound showed effective colorimetric single selectivity and high sensitivity for aluminum cation in CH3CN/H2O (1:3) binary solutions. The detection limit is 1.0×10(-8) M Al(3+) based on UV-vis changes.

摘要

一种新型的比色传感器,2-羟基萘甲醛异烟酰腙(HINH),可以通过异烟肼和 2-羟基-1-萘甲醛的缩合反应轻松合成。所制备的化合物在 CH3CN/H2O(1:3)二元溶液中对铝阳离子表现出有效的比色单选择性和高灵敏度。基于紫外-可见变化,检测限为 1.0×10(-8) M Al(3+)。

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