Key Laboratory of Bio-Based Material Science and Technology, Ministry of Education, Northeast Forestry University, Harbin 150040, China.
Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803, USA.
Carbohydr Polym. 2015 Sep 5;128:24-31. doi: 10.1016/j.carbpol.2015.04.014. Epub 2015 Apr 23.
A composite filter paper with super-hydrophobicity was obtained by adhering micro/nano structure of amorphous titanium dioxide on the filter paper surface with modifying low surface energy material. By virtue of the coupling agent, which plays an important part in bonding amorphous titanium dioxide and epoxy resin, the structure of super-hydrophobic thin film on the filter paper surface is extremely stable. The microstructure of super-hydrophobic filter paper was characterized by scanning electron microscopy (SEM), the images showed that the as-prepared filter paper was covered with uniform amorphous titanium dioxide particles, generating a roughness structure on the filter paper surface. The super-hydrophobic performance of the filter paper was characterized by water contact angle measurements. The observations showed that the wettability of filter paper samples transformed from super-hydrophilicity to super-hydrophobicity with the water contact angle of 153 ± 1°. Some experiments were also designed to test the effect of water-oil separation and UV-resistant by the super-hydrophobic filter paper. The prepared super-hydrophobic filter paper worked efficiently and simply in water-oil separation as well as enduringly in anti-UV property after the experiments. This method offers an opportunity to the practical applications of the super-hydrophobic filter paper.
一种具有超亲水性的复合滤纸,通过在滤纸表面附着具有低表面能材料的无定形二氧化钛的微/纳结构来获得。凭借偶联剂在连接无定形二氧化钛和环氧树脂方面的重要作用,滤纸表面超疏水薄膜的结构极其稳定。通过扫描电子显微镜(SEM)对超疏水滤纸的微观结构进行了表征,图像显示,所制备的滤纸表面覆盖着均匀的无定形二氧化钛颗粒,在滤纸表面产生了粗糙结构。通过水接触角测量对滤纸的超疏水性进行了表征。观察表明,随着水接触角从 153±1°变为 153±1°,滤纸样品的润湿性从超亲水性变为超疏水性。还设计了一些实验来测试超疏水滤纸的油水分离和耐紫外线的效果。经过实验,制备的超疏水滤纸在油水分离方面效果显著,且在抗紫外线性能方面持久耐用。这种方法为超疏水滤纸的实际应用提供了机会。