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混合植物化学物质介导合成用于葡萄糖氧化和抗菌应用的多功能银-金-钯纳米颗粒

Mixed Phytochemicals Mediated Synthesis of Multifunctional Ag-Au-Pd Nanoparticles for Glucose Oxidation and Antimicrobial Applications.

作者信息

Rao K Jagajjanani, Paria Santanu

机构信息

Interfaces and Nanomaterials Laboratory, Department of Chemical Engineering, National Institute of Technology, Rourkela-769 008, Orissa India.

出版信息

ACS Appl Mater Interfaces. 2015 Jul 1;7(25):14018-25. doi: 10.1021/acsami.5b03089. Epub 2015 Jun 16.

Abstract

The growing awareness toward the environment is increasing commercial demand for nanoparticles by green route syntheses. In this study, alloy-like Ag-Au-Pd trimetallic nanoparticles have been prepared by two plants extracts Aegle marmelos leaf (LE) and Syzygium aromaticum bud extracts (CE). Compositionally different Ag-Au-Pd nanoparticles with an atomic ratio of 5.26:2.16:1.0 (by LE) and 11.36:13.14:1.0 (by LE + CE) of Ag:Au:Pd were easily synthesized within 10 min at ambient conditions by changing the composition of phytochemicals. The average diameters of the nanoparticles by LE and LE + CE are ∼8 and ∼11 nm. The catalytic activity of the trimetallic nanoparticles was studied, and they were found to be efficient catalysts for the glucose oxidation process. The prepared nanoparticles also exhibited efficient antibacterial activity against a model Gram-negative bacteria Escherichia coli. The catalytic and antimicrobial properties of these readymade trimetallic nanoparticles have high possibility to be utilized in diverse fields of applications such as health care to environmental.

摘要

人们对环境的关注度不断提高,这使得通过绿色路线合成纳米颗粒的商业需求日益增加。在本研究中,通过两种植物提取物——余甘子叶(LE)提取物和丁香花蕾提取物(CE)制备了类合金Ag-Au-Pd三金属纳米颗粒。通过改变植物化学物质的组成,在环境条件下10分钟内即可轻松合成原子比为5.26:2.16:1.0(由LE制备)和11.36:13.14:1.0(由LE + CE制备)的成分不同的Ag-Au-Pd纳米颗粒。由LE和LE + CE制备的纳米颗粒的平均直径分别约为8纳米和11纳米。研究了三金属纳米颗粒的催化活性,发现它们是葡萄糖氧化过程的高效催化剂。所制备的纳米颗粒还对模式革兰氏阴性菌大肠杆菌表现出高效抗菌活性。这些现成的三金属纳米颗粒的催化和抗菌特性极有可能应用于从医疗保健到环境等不同领域。

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