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指纹构成与老化:文献综述

Fingerprint composition and aging: A literature review.

作者信息

Cadd Samuel, Islam Meez, Manson Peter, Bleay Stephen

机构信息

School of Science and Engineering, Teesside University, Borough Road, Middlesbrough TS1 3BA, United Kingdom.

School of Science and Engineering, Teesside University, Borough Road, Middlesbrough TS1 3BA, United Kingdom.

出版信息

Sci Justice. 2015 Jul;55(4):219-38. doi: 10.1016/j.scijus.2015.02.004. Epub 2015 Mar 13.

Abstract

Fingerprints have a key role in criminal investigations and are the most commonly used form of evidence worldwide. Significant gaps remain however, in the understanding of fingerprint chemistry, including enhancement reaction mechanisms and the effect of environmental variables and time on composition. Determining the age of a fingerprint is also a relatively unexplored area. A successful method, with reliable and quantitative estimates, would have numerous advantages. Previous unreliable methods have predominantly focused on enhancement success based on physical and chemical changes. This review explores variations in composition due to donor characteristics and environmental variables, and identifies gaps for further research. We also present a qualitative and quantitative summary of the effect of time on composition. Kinetics are presented where known, with summary schematics for reaction mechanisms. Previous studies exploring methods for determining the age of a fingerprint are also discussed, including their advantages and disadvantages. Lastly we propose a potentially more accurate and reliable methodology for determining fingerprint age based on quantitative kinetic changes to the composition of a fingerprint over time.

摘要

指纹在刑事调查中起着关键作用,是全球最常用的证据形式。然而,在指纹化学的理解方面仍存在重大差距,包括增强反应机制以及环境变量和时间对成分的影响。确定指纹的形成时间也是一个相对未被探索的领域。一种成功的方法,能够进行可靠且定量的估计,将具有诸多优势。以往不可靠的方法主要集中在基于物理和化学变化的增强效果上。本综述探讨了由于供体特征和环境变量导致的成分变化,并确定了有待进一步研究的空白。我们还对时间对成分的影响进行了定性和定量总结。在已知动力学的情况下给出了动力学内容,并附有反应机制的示意图总结。还讨论了以往探索确定指纹形成时间方法的研究,包括其优缺点。最后,我们基于指纹成分随时间的定量动力学变化,提出了一种可能更准确、更可靠的确定指纹形成时间的方法。

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