Department of Chemistry, Ludwig Maximilian University, Butenandtstrasse 5-13 (D), 81377 München (Germany) http://www.hedm.cup.uni-muenchen.de.
Angew Chem Int Ed Engl. 2015 Aug 24;54(35):10299-302. doi: 10.1002/anie.201502919. Epub 2015 Jun 19.
Highly energetic 1,5-di(nitramino)tetrazole and its salts were synthesized. The neutral compound is very sensitive and one of the most powerful non-nuclear explosives to date. Selected nitrogen-rich and metal salts were prepared. The potassium salt can be used as a sensitizer in place of tetracene. The obtained compounds were characterized by low-temperature X-ray diffraction, IR and Raman spectroscopy, multinuclear NMR spectroscopy, elemental analysis, and DSC. Calculated energetic performances using the EXPLO5 code based on calculated (CBS-4M) heats of formation and X-ray densities support the high energetic performances of the 1,5-dinitraminotetrazolates as energetic materials. The sensitivities towards impact, friction, and electrostatic discharge were also explored.
高能量 1,5-二（硝氨基）四唑及其盐类被合成。该中性化合物非常敏感，是迄今为止最强大的非核爆炸物之一。选择了富氮和金属盐类进行制备。钾盐可用作取代苝的敏化剂。通过低温 X 射线衍射、IR 和拉曼光谱、多核 NMR 光谱、元素分析和 DSC 对获得的化合物进行了表征。使用基于计算（CBS-4M）生成热和 X 射线密度的 EXPLO5 代码计算得到的能量性能，支持了 1,5-二硝氨基四唑盐作为高能材料的高能量性能。还研究了它们对冲击、摩擦和静电放电的敏感性。
