可见光光氧化还原催化：通过级联C-S/C-C形成过程由N-芳基丙烯酰胺和芳基亚磺酸直接合成磺化氧化吲哚。
Visible-Light Photoredox Catalysis: Direct Synthesis of Sulfonated Oxindoles from N-Arylacrylamides and Arylsulfinic Acids by Means of a Cascade C-S/C-C Formation Process.
作者信息
Xia Dong, Miao Tao, Li Pinhua, Wang Lei
机构信息
Department of Chemistry, Huaibei Normal University, Huaibei, Anhui, 235000, P.R. China.
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Shanghai, 200032, P.R. China.
出版信息
Chem Asian J. 2015 Sep;10(9):1919-25. doi: 10.1002/asia.201500498. Epub 2015 Jul 29.
PMID:26097076
Abstract
A novel photocatalytic synthesis of sulfonated oxindoles from N-arylacrylamides and arylsulfinic acids was developed by means of a cascade C-S/C-C bond-formation process. This method provides mild, efficient, and atom-economical access to various sulfonated oxindoles in water.
摘要
通过级联C-S/C-C键形成过程，开发了一种由N-芳基丙烯酰胺和芳基亚磺酸光催化合成磺化氧化吲哚的新方法。该方法为在水中温和、高效且原子经济地合成各种磺化氧化吲哚提供了途径。
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