中药蟾酥中的生物碱：通过合成实现将蟾酥酰胺结构重新确定为蟾酥色胺C。
Alkaloids from the Traditional Chinese Medicine ChanSu: synthesis-enabled structural reassignment of bufopyramide to bufoserotonin C.
作者信息
Davison Emma K, Sperry Jonathan
机构信息
School of Chemical Sciences, The University of Auckland, 23 Symonds Street, Auckland, 1010, New Zealand.
出版信息
Org Biomol Chem. 2015 Aug 7;13(29):7911-4. doi: 10.1039/c5ob01051a. Epub 2015 Jun 24.
PMID:26106975
Abstract
A synthesis of putative bufopyramide has shown the structure assigned to the natural product to be incorrect. The spectroscopic data for the natural product bufopyramide matches that obtained from a synthetic sample of bufoserotonin C, confirming that the two natural products are not distinct, but instead the same compound.
摘要
推定的蟾吡胺的合成表明，赋予该天然产物的结构是不正确的。天然产物蟾吡胺的光谱数据与从蟾毒色胺C的合成样品中获得的数据相匹配，证实这两种天然产物并非不同，而是同一化合物。
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