路易斯酸辅助的铁催化醇的胺化反应
Iron-catalyzed amination of alcohols assisted by Lewis acid.
作者信息
Pan Hui-Jie, Ng Teng Wei, Zhao Yu
机构信息
Department of Chemistry, National University of Singapore, 3 Science Drive 3, 117543, Republic of Singapore.
出版信息
Chem Commun (Camb). 2015 Jul 28;51(59):11907-10. doi: 10.1039/c5cc03399c.
PMID:26111504
Abstract
An efficient Lewis acid-assisted, iron-catalyzed amination of alcohols using borrowing hydrogen methodology was developed. In particular, silver fluoride was identified to be a highly effective additive to overcome the low efficiency in the amination of secondary alcohols catalyzed by Knölker's complex.
摘要
开发了一种高效的路易斯酸辅助、铁催化的醇类借氢胺化反应方法。特别地，已确定氟化银是一种高效添加剂，可克服克诺克配合物催化仲醇胺化反应效率低下的问题。
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