Marichev Kostiantyn O, Takacs James M
Department of Chemistry, University of Nebraska-Lincoln, Lincoln, Nebraska 68588-0304, United States.
ACS Catal. 2016 Apr 1;6(4):2205-2210. doi: 10.1021/acscatal.6b00175. Epub 2016 Feb 23.
A new ruthenium complex catalyzes the amination of primary and secondary alcohols and the regioselective mono- and sequential diamination of diols via the borrowing hydrogen pathway. Several variations on new intra- and intermolecular cyclizations of aminoalcohols, diols and diamines lead to heterocyclic ring systems.
一种新型钌配合物通过借氢途径催化伯醇和仲醇的胺化反应以及二醇的区域选择性单胺化和连续二胺化反应。氨基醇、二醇和二胺的新型分子内和分子间环化反应的多种变体可生成杂环体系。