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使用半导体光催化剂粉末进行太阳能水分解

Solar Water Splitting Using Semiconductor Photocatalyst Powders.

作者信息

Takanabe Kazuhiro

机构信息

Division of Physical Sciences and Engineering, KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology (KAUST), 4700 KAUST, Thuwal, 23955-6900, Saudi Arabia.

出版信息

Top Curr Chem. 2016;371:73-103. doi: 10.1007/128_2015_646.

Abstract

Solar energy conversion is essential to address the gap between energy production and increasing demand. Large scale energy generation from solar energy can only be achieved through equally large scale collection of the solar spectrum. Overall water splitting using heterogeneous photocatalysts with a single semiconductor enables the direct generation of H2 from photoreactors and is one of the most economical technologies for large-scale production of solar fuels. Efficient photocatalyst materials are essential to make this process feasible for future technologies. To achieve efficient photocatalysis for overall water splitting, all of the parameters involved at different time scales should be improved because the overall efficiency is obtained by the multiplication of all these fundamental efficiencies. Accumulation of knowledge ranging from solid-state physics to electrochemistry and a multidisciplinary approach to conduct various measurements are inevitable to be able to understand photocatalysis fully and to improve its efficiency.

摘要

太阳能转换对于解决能源生产与不断增长的需求之间的差距至关重要。大规模太阳能发电只能通过同样大规模地收集太阳光谱来实现。使用单一半导体的多相光催化剂进行整体水分解能够使光反应器直接产生氢气,并且是大规模生产太阳能燃料最经济的技术之一。高效的光催化剂材料对于使这一过程在未来技术中可行至关重要。为了实现用于整体水分解的高效光催化,由于整体效率是所有这些基本效率相乘得到的,所以在不同时间尺度上涉及的所有参数都应得到改善。要能够充分理解光催化并提高其效率,积累从固态物理到电化学等方面的知识以及采用多学科方法进行各种测量是必不可少的。

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