Key Laboratory of Modern Acoustics, MOE, Institute of Acoustics, School of Physics, Nanjing University, Nanjing 210093, P. R. China.
Chem Commun (Camb). 2015 Sep 7;51(69):13354-7. doi: 10.1039/c5cc03905c.
Here we report multilayer hollow spheres consisting of alternating ultrathin Ti0.91O2 nanosheets and CdS nanoparticles via exquisite layer-by-layer self-assembly to achieve an all solid-state Z-scheme system with 7-times enhancement of the CH4-production rate relative to pure Ti0.91O2 hollow spheres, due to a greatly prolonged lifetime of charge carriers.
在此,我们通过精巧的层层自组装报告了由交替的超薄 Ti0.91O2 纳米片和 CdS 纳米颗粒组成的多层空心球,以实现全固态 Z 型体系,与纯 Ti0.91O2 空心球相比,CH4 生成速率提高了 7 倍,这归因于载流子寿命的大大延长。