Rh(III) -Catalyzed C-H Olefination of Benzoic Acids under Mild Conditions using Oxygen as the Sole Oxidant.
作者信息
Jiang Quandi, Zhu Changlei, Zhao Huaiqing, Su Weiping
机构信息
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155, Fuzhou, Fujian, 350002, China.
出版信息
Chem Asian J. 2016 Feb 4;11(3):356-9. doi: 10.1002/asia.201500601. Epub 2015 Jul 28.
PMID:26174977
Abstract
Phthalide skeletons have been synthesized for the first time through a Rh(III) -catalyzed C-H olefination of benzoic acids under mild conditions using oxygen as the sole oxidant. Aromatic acids bearing a variety of functional groups could react with diverse alkenes to afford the desired cyclized lactones or uncyclized alkenylarenes in moderate-to-excellent yields.
摘要
Zotero 插件