氧化反应中的单核非血红素铁（IV）-氧和锰（IV）-氧配合物：实验结果证实理论预测。
Mononuclear nonheme iron(IV)-oxo and manganese(IV)-oxo complexes in oxidation reactions: experimental results prove theoretical prediction.
作者信息
Chen Junying, Cho Kyung-Bin, Lee Yong-Min, Kwon Yoon Hye, Nam Wonwoo
机构信息
Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750, Korea.
出版信息
Chem Commun (Camb). 2015 Aug 25;51(66):13094-7. doi: 10.1039/c5cc04217h.
Reactivities of mononuclear nonheme iron(IV)-oxo and manganese(IV)-oxo complexes bearing a pentadentate N4Py ligand, M(IV)O(N4Py) (M = Fe and Mn), are compared in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; theoretical and experimental results show that Fe(IV)O is more reactive than Mn(IV)O. The latter is shown to react through excited state reactivity (ESR).
比较了带有五齿N4Py配体的单核非血红素铁（IV）-氧和锰（IV）-氧配合物[M（IV）O（N4Py）]（2+）（M = Fe和Mn）在氢原子转移（HAT）和氧原子转移（OAT）反应中的反应活性；理论和实验结果表明，Fe（IV）O比Mn（IV）O更具反应活性。研究表明，后者通过激发态反应性（ESR）发生反应。
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