基于二丙基硫醚与氯化铝络合作用的新型离子液体用于铝的电沉积
New ionic liquids based on the complexation of dipropyl sulfide and AlCl3 for electrodeposition of aluminum.
作者信息
Fang Youxing, Jiang Xueguang, Sun Xiao-Guang, Dai Sheng
机构信息
Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA.
出版信息
Chem Commun (Camb). 2015 Sep 4;51(68):13286-9. doi: 10.1039/c5cc05233e.
PMID:26201079
Abstract
A new kind of ionic liquid based on the complexation of dipropyl sulfide (DPS) and AlCl3 has been prepared. The equivalent concentration of AlCl3 in the ionic liquid is as high as 2.3 M. More importantly, it is highly fluidic and exhibits an ambient ionic conductivity of 1.25 × 10(-4) S cm(-1). This new ionic liquid can be successfully used as an electrolyte for electrodeposition of aluminum.
摘要
一种基于二丙基硫醚（DPS）与三氯化铝络合作用制备的新型离子液体已被制备出来。该离子液体中三氯化铝的当量浓度高达2.3 M。更重要的是，它具有高流动性，且在室温下的离子电导率为1.25×10⁻⁴ S cm⁻¹。这种新型离子液体可成功用作铝电沉积的电解质。
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