El Abedin Sherif Zein, Endres Frank
Faculty of Natural and Materials Sciences, Clausthal University of Technology, Robert-Koch-Strasse 42, 38678 Clausthal-Zellerfeld, Germany.
Acc Chem Res. 2007 Nov;40(11):1106-13. doi: 10.1021/ar700049w. Epub 2007 May 24.
Due to their wide thermal windows, ionic liquids can be regarded as the missing link between aqueous/organic solutions and high-temperature molten salts. They can be employed efficiently for the coating of other metals with thin layers of tantalum, aluminum, and presumably many others at reasonable temperatures by electrochemical means. The development of ionic liquids, especially air and water stable ones, has opened the door for the electrodeposition of reactive elements such as, for example, Al, Ta, and Si, which in the past were only accessible using high-temperature molten salts or, in part, organic solvents.
由于其较宽的热窗口,离子液体可被视为水溶液/有机溶液与高温熔盐之间缺失的环节。通过电化学方法,它们可以在合理的温度下有效地用于用钽、铝以及可能还有许多其他金属的薄层涂覆其他金属。离子液体的发展,特别是空气和水稳定的离子液体,为诸如铝、钽和硅等活性元素的电沉积打开了大门,这些元素过去只能使用高温熔盐或部分有机溶剂来获得。