二甲基锌介导的自由基反应探索。
Exploration of Dimethylzinc-Mediated Radical Reactions.
机构信息
Graduate School of Pharmaceutical Sciences, Kyoto University, Kyoto, Japan.
Department of Medicinal Chemistry, Faculty of Pharmaceutical Sciences, Doshisha Women's College of Liberal Arts, Kyoto, Japan.
出版信息
Chem Rec. 2015 Oct;15(5):854-71. doi: 10.1002/tcr.201500017. Epub 2015 Jul 17.
PMID:26201084
Abstract
In this account, our studies on radical reactions that are promoted by dimethylzinc and air are described. Advantages of this reagent and differences from conventional radical initiators, such as triethylborane, are discussed.
摘要
在本报告中，我们描述了由二甲基锌和空气促进的自由基反应的研究。讨论了这种试剂的优点以及与传统自由基引发剂（如三乙基硼烷）的区别。
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