Shi Xiaodi, Dou Renmei, Ma Tianze, Liu Weiyi, Lu Xihua, Shea Kenneth J, Song Yanlin, Jiang Lei
College of Chemistry, Chemical Engineering and Biotechnology, Donghua University , Shanghai 201620, People's Republic of China.
Key Laboratory of Organic Solid, Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences , Beijing 100190, People's Republic of China.
ACS Appl Mater Interfaces. 2015 Aug 26;7(33):18424-8. doi: 10.1021/acsami.5b04499. Epub 2015 Aug 11.
The sensitivity of long persistent phosphor materials (LPP) to moisture greatly limits their applications especially in humid environments, which cause the hydrolysis of LPP and shorten their lifetime. In this work, a facile, environmentally friendly, and low-cost method was developed to prevent the infiltration of water or moisture to the LPP by doping LPP with SiO2 nanoparticles to form a superhydrophobic coating. The superhydrophobic coating provided a stable environment to the self-illuminous system, which not only can resist the infiltration of water but also can have good self-cleaning property, similar to the lotus leaf effect. This facile method will be very beneficial for expending further application of LPP especially in high humidity.
长余辉磷光材料(LPP)对水分的敏感性极大地限制了它们的应用,尤其是在潮湿环境中,这会导致LPP水解并缩短其寿命。在这项工作中,开发了一种简便、环保且低成本的方法,通过用二氧化硅纳米颗粒掺杂LPP以形成超疏水涂层,来防止水或湿气渗透到LPP中。该超疏水涂层为自发光系统提供了一个稳定的环境,其不仅能够抵抗水的渗透,还具有良好的自清洁性能,类似于荷叶效应。这种简便的方法对于扩大LPP的进一步应用,尤其是在高湿度环境下的应用将非常有益。