School of Physics and Information Technology, Shaanxi Normal University, Xi'an, 710119, P. R. China.
Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou, 215123, P. R. China.
Macromol Rapid Commun. 2019 Mar;40(6):e1800708. doi: 10.1002/marc.201800708. Epub 2018 Nov 23.
Transparent coatings with antireflection, antifogging, antifrosting, antifouling, and moisture self-cleaning properties can dramatically improve the efficiency and convenience of optical elements and thus are highly desirable for practical applications. Here, it is demonstrated that a bionic nanocone surface (BNS) fabricated by a facile, low-cost process consisting of template-assisted prepolymer curing followed by surface modification can possess the multiple functions listed above. The polymer coating firmly adheres to a glass substrate due to bonding agents. After SiO nanoparticle deposition and low-surface-energy fluorosilane modification, the coating shows low microdroplet adhesion. As a result, the as-prepared BNS exhibits a high transmittance when exposed to fog and good clarity even when the temperature decreases to -20 °C in a humid environment. Dipping the BNS into exemplified graphite powder has almost no influence on the transparency, and the BNS can realize self-cleaning of moisture when the surface is covered with a thick layer of man-made contaminants.
具有抗反射、防雾、防霜、防污和自湿清洁功能的透明涂层可以显著提高光学元件的效率和便利性,因此在实际应用中非常理想。在这里,通过一种简单、低成本的工艺(包括模板辅助预聚物固化和表面改性)制备仿生纳米锥形表面(BNS),可以使其具有上述多种功能。由于键合剂的存在,聚合物涂层可以牢固地附着在玻璃基底上。在沉积 SiO2 纳米颗粒和低表面能氟硅烷改性后,涂层表现出低的微液滴附着力。因此,所制备的 BNS 在暴露于雾中时表现出高透过率,并且即使在潮湿环境中温度降至-20°C 时也具有良好的清晰度。将 BNS 浸入示例石墨粉中几乎不会影响其透明度,并且当表面覆盖有一层厚厚的人造污染物时,BNS 可以实现水分的自清洁。