Ray Krishanu, Badugu Ramachandram, Szmacinski Henryk, Lakowicz Joseph R
Centre for Fluorescence Spectroscopy, University of Maryland School of Medicine, Department of Biochemistry and Molecular Biology, 725 West Lombard Street, Baltimore, MD 21201, USA.
Chem Commun (Camb). 2015 Oct 18;51(81):15023-6. doi: 10.1039/c5cc03581c.
We observed over 400-fold enhanced fluorescence from single Cy5 molecules assembled on multilayer silver nanoparticle-dielectric-metal (PDM) substrate. This substantial enhancement is due to the near-field enhanced excitation, emission, and interaction of Cy5 with plasmonic nanostructures. Experimental observation is supported by finite-element method calculations.
我们观察到,在多层银纳米颗粒-电介质-金属(PDM)衬底上组装的单个Cy5分子的荧光增强了400多倍。这种显著的增强是由于近场增强了Cy5与等离子体纳米结构的激发、发射和相互作用。有限元法计算支持了实验观察结果。