铁配位络合物催化的烷基C-H键选择性氧化研究进展

Recent Advances in the Selective Oxidation of Alkyl C-H Bonds Catalyzed by Iron Coordination Complexes.

作者信息

Canta Mercè, Rodríguez Mònica, Costas Miquel

机构信息

Departament de Química i Institut de Química Computacional i Catàlisi, Universitat de Girona, Facultat de Ciències, Campus de Montilivi, 17071, Girona, Catalonia, Spain.

出版信息

Top Curr Chem. 2016;372:27-54. doi: 10.1007/128_2015_659.

DOI:10.1007/128_2015_659

PMID:26318344

Abstract

Selective and stereoretentive oxidation of alkyl C-H bonds has been described over the last decade by employing biologically inspired iron coordination complexes as catalysts and hydrogen peroxide as oxidant. Examples of catalyst dependent C-H site selectivity have started to appear. The current paper describes an account of these findings.

摘要

在过去十年中，通过使用受生物启发的铁配位络合物作为催化剂以及过氧化氢作为氧化剂，已实现了烷基C-H键的选择性和立体保持性氧化。依赖于催化剂的C-H位点选择性的例子已开始出现。本文描述了这些研究结果。