Cu(I)-USY 作为一种无配体、可回收的催化体系用于 UIlmann 型二芳基醚的合成。
Cu(I)-USY as a Ligand-Free and Recyclable Catalytic System for the Ullmann-Type Diaryl Ether Synthesis.
机构信息
Institut des Technologies Avancées en sciences du Vivant (ITAV) - Centre Pierre Potier, CNRS-USR3505, Université de Toulouse , 1 place Pierre Potier, BP 50624, Toulouse, 31106 Cedex 1, France.
LAboratoire de SYnthèse, Réactivité Organique et Catalyse (LASYROC) - Institut de Chimie, CNRS-UMR7177, Université de Strasbourg , 4 rue Blaise Pascal, 67070 Strasbourg, France.
出版信息
Org Lett. 2015 Sep 18;17(18):4494-7. doi: 10.1021/acs.orglett.5b02167. Epub 2015 Aug 31.
The catalytic potential of copper(I)-exchanged zeolites was evaluated in the Ullmann-type synthesis of diaryl ethers. Among four investigated zeolites (i.e., USY, MOR, β, and ZSM5), Cu(I)-USY was the best catalyst and proved efficient under ligand-free conditions in toluene at 120 °C. Cu(I)-USY was also easy to recover and was recyclable up to five times without significant loss of activity.
研究了铜（I）交换沸石在Ullmann 型二芳基醚合成中的催化潜力。在所研究的四种沸石（USY、MOR、β 和 ZSM5）中，Cu（I）-USY 是最好的催化剂，在无配体条件下于 120°C 的甲苯中表现出高效。Cu（I）-USY 易于回收，可重复使用多达 5 次，活性损失不明显。
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