三（三甲基硅基）硅烷与可见光照射：一种用于合成吲哚和氧化吲哚的新型无金属无添加剂光化学过程。
Tris(trimethylsilyl)silane and visible-light irradiation: a new metal- and additive-free photochemical process for the synthesis of indoles and oxindoles.
作者信息
da Silva Gustavo Piva, Ali Akbar, da Silva Rodrigo César, Jiang Hao, Paixão Márcio W
机构信息
Departamento de Química, Universidade Federal de São Carlos, São Carlos, 97105-900, SP, Brazil.
出版信息
Chem Commun (Camb). 2015 Oct 21;51(82):15110-3. doi: 10.1039/c5cc06329a.
A combined tris(trimethylsilyl)silane and visible-light-promoted intramolecular reductive cyclization protocol for the synthesis of indoles and oxindoles has been developed. This straightforward and efficient method shows tolerance towards a broad spectrum of functional-groups and enables rapid and practical synthesis of functionalized nitrogen-based heterocycles in high yields under additive and metal-free, mild photochemical conditions.
已开发出一种用于合成吲哚和氧化吲哚的三（三甲基硅基）硅烷与可见光促进的分子内还原环化相结合的方法。这种直接且高效的方法对多种官能团具有耐受性，并且能够在无添加剂和无金属的温和光化学条件下，以高产率快速且实际地合成功能化的含氮杂环化合物。
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