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钴负载量对碳化硅负载催化剂上费托合成的影响。

The Effect of Cobalt Loading on Fischer Tropsch Synthesis Over Silicon Carbide Supported Catalyst.

作者信息

Lee Jae Suk, Jung Jae Sun, Moon Dong Ju

出版信息

J Nanosci Nanotechnol. 2015 Jan;15(1):396-9. doi: 10.1166/jnn.2015.8350.

Abstract

A series of Co (5-30 wt%) based SiC supported catalysts were prepared by impregnation method and investigated for FTS reaction. The FTS reaction was carried out in a fixed bed reactor system with the H2/CO molar ratio of 2, reaction temperature of 230 degrees C and reaction pressure of 20 bar for 120 h. All catalysts were characterized by N2 physisorption, XRD, TPR, SEM and TEM techniques. It was found that 15 wt% Co/SiC catalyst showed better catalytic performance with high selectivity of C(5+) hydrocarbons than the other catalysts. The results, suggest that the catalytic performance of the catalysts depends on average pore size of support and surface density of cobalt, metal and support interactions.

摘要

通过浸渍法制备了一系列钴含量为5 - 30 wt%的碳化硅负载催化剂,并对其进行费托合成反应研究。费托合成反应在固定床反应器系统中进行,氢气/一氧化碳摩尔比为2,反应温度为230℃,反应压力为20巴,反应120小时。所有催化剂均采用氮气物理吸附、X射线衍射、程序升温还原、扫描电子显微镜和透射电子显微镜技术进行表征。结果发现,15 wt%的钴/碳化硅催化剂表现出比其他催化剂更好的催化性能,对C(5+)烃具有高选择性。结果表明,催化剂的催化性能取决于载体的平均孔径以及钴的表面密度、金属与载体之间的相互作用。

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