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用于微生物燃料电池的聚吡咯涂层碳纳米管复合电极

Carbon Nanotube Composite Electrode Coated with Polypyrrole for Microbial Fuel Cell Application.

作者信息

Roh Sung-Hee, Woo Hee-Gweon

出版信息

J Nanosci Nanotechnol. 2015 Jan;15(1):484-7. doi: 10.1166/jnn.2015.8404.

Abstract

Microbial fuel cells (MFCs) are bio-electrochemical system that can convert biomass spontaneously into electricity through the metabolic activity of microorganisms. We constructed MFCs of polypyrrole (PPy) coated carbon nanotube (CNT) composite as an electrode material and Shewanella oneidensis as the biocatalyst to increase power density. The PPy-coated CNT were synthesized by the in-situ chemical polymerization of pyrrole on CNT, and the electrochemical properties and performance of the modified electrode as an anode in MFC were then investigated. Treatment with 0.1 wt% Ge-132 on the acid-treated MWNTs helped to form better PPy-MWNT composite. The PPy-CNT/CF anode showed a noteworthy 38% power production improvement when compared to plain CF anode. The PPy-CNT composite could be a very efficient and promising electrode material for electricity generation of MFC.

摘要

微生物燃料电池(MFCs)是一种生物电化学系统,它可以通过微生物的代谢活动将生物质自发地转化为电能。我们构建了以聚吡咯(PPy)包覆碳纳米管(CNT)复合材料作为电极材料、希瓦氏菌作为生物催化剂的微生物燃料电池,以提高功率密度。通过在碳纳米管上原位化学聚合吡咯来合成聚吡咯包覆的碳纳米管,然后研究了该修饰电极作为微生物燃料电池阳极的电化学性质和性能。用0.1 wt%的Ge-132处理酸处理过的多壁碳纳米管有助于形成更好的聚吡咯-多壁碳纳米管复合材料。与普通碳毡阳极相比,聚吡咯-碳纳米管/碳毡阳极的发电量显著提高了38%。聚吡咯-碳纳米管复合材料可能是一种用于微生物燃料电池发电的非常高效且有前景的电极材料。

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